I don't know of any site that specifically does this for particular tournaments. But its very easy to do this yourself! Here's how you do it:
a) Download Scid vs Pc software (http://scidvspc.sourceforge.net/)
b) Download pgn for the Olympiad in Tromso 2014 from TWIC (http://www.theweekinchess.com/assets/files/pgn/olym14.pgn)
c) Open a new DB in SCID vs PC software and import this PGN.
d) Go to Tools > Opening Report
or
Windows > Tree Window
to get the opening tree and the percentages
Here's the output from Olympiad 2014 taken from Scid vs PC:
4.2 Moves from the report position
Move Frequency Score AvElo Perf AvYear Draw ECO
1: e4 1649: 43.6% 52.5% 2275 2313 2014 23% B00a
2: d4 1404: 37.1% 52.7% 2327 2343 2014 29% A40a
3: Nf3 363: 9.6% 60.0% 2346 2405 2014 24% A04
4: c4 248: 6.5% 52.0% 2319 2324 2014 27% A10
5: [end] 45: 1.1% 35.5% 2197 2058 2014 0% A00a
6: b3 17: 0.4% 55.8% 2329 2202 2014 18% A01
7: f4 15: 0.3% 33.3% 2152 2127 2014 13% A02
8: g3 12: 0.3% 66.6% 2411 2399 2014 33% A00t
9: Nc3 8: 0.2% 62.5% 2014 25% A00l
10: b4 7: 0.1% 78.5% 2014 14% A00p
11: e3 3: 0.0% 33.3% 2014 67% A00k
12: d3 2: 0.0% 0.0% 2014 0% A00j
13: f3 1: 0.0% 100.0% 2014 0% A00b
14: Na3 1: 0.0% 50.0% 2014 100% A00h
15: h3 1: 0.0% 100.0% 2014 0% A00d
__________________________________________________________________
TOTAL: 3776:100.0% 53.1% 2304 2326 2014 26%
4.3 Positional Themes
Frequency of themes in the first 20 moves of each game:
Same-side castling: 73% White Isolated Queen Pawn: 8%
Opposite castling: 8% Black Isolated Queen Pawn: 8%
Kingside pawn storm: 15% White Pawn on 5/6/7th rank: 52%
Queens exchanged: 40% Black Pawn on 2/3/4th rank: 34%
Only one side has Bishop pair: 6% Open c/d/e file: 50%